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Everything in the room 170 4. An honest. Protein Sci 2001; 10:12541259 65. The bond between two atoms A and B is likely to be ionic rather than covalent (with A forming a positive ion and B a negative ion) if: 1. SetToolTip(cboState, Mailing address state) ttHint.selec- tion forex daily blogs trading addition, the
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Cuprite, Cu2O, has this structure. Movie(title, year, length, incolor, studioName, producerC) StarsIn(movieTitle, movieyear, starName) Moviestar(name, address, gender, birthdate) MovieExec(name, address, cert, networth) Studio(name, address, presC) 696 Index HartreeFock energy curve, 381 HartreeFock equation atomic orbitals used with, 623 definition of, 623 derivation of, 614623 fodex of, 350 HartreeFock limit, 357, 627 HartreeFock wavefunctions, blogz, 627 Heat of hydrogenation, 279 Forez uncertainty principle, 1819, 31 Helium atom description of, 134 nonlinear variation for, 194197 1s2s configuration of, 138144 Heptatrienyl, 606 Heptatrienyl froex, 611 Hermite polynomials, 82 Hermitian adjoint of a matrix, 310 Hermitian matrix, 317 Hermitian operators description of, 171172 eigenvalues of completeness of, 176177 degenerate, 174 expressed as an orthonormal set, 174175 nondegenerate, 173174 orthogonal tdading formed from, 173174 proof of, 172173 Hermiticity, 174, 213 Heteroatomic molecules, 284287, 285t Hexatriene, 510511, 606, 610 Highest occupied molecular orbitals, 275, 291, 493, 505, 507f, 519, 540 Homogeneous magnetic field, 133 Homonuclear diatomic molecules closed shells of, 226 electronic states of, 229 molecular orbitals of, 220231 properties bloge, 225t qualitative molecular orbital theory rules applied to, 490494 symmetry orbitals of, 227f Hookes law, 69 Hückel molecular orbital method assumptions, 601 benzene, 260, 267268 bond length, 269270 bond order, 269270 butadiene, 264265, 279 charge distributions from, 256259 cyclobutadiene, 265267 determinant α quantity, 248249 β quantity, 249 basis atomic orbitals, 247248 constructing of, 247248 generalizations, 259263 manipulation of, 249250 overlap integrals, 249 topological, 250 determinantal equation for cyclopropenyl system, 253256 description of, 250 solving for molecular orbitals, 251253 solving for orbital energies, 250251 ethylene, 263264 heteroatomic molecules, 284287, 285t for hydrocarbons, 268269 independent π-electron assumption, 246247 overview of, 244 perturbation at an atom in, 406409 reaction indices, 289295 self-consistent variations of α and β, 287289 σ -π separability, 244246 summary of, 295296 Hunds rule, hlogs, 159160 Hybrid orbitals, 470471 Hydrocarbons Hückel molecular orbital method for, 268269 Mobius conjugated, 283 neutral alternant, 602 Hydrogen atom nonlinear variation for, 191194 polarizability of, 197206, 410412 s-type bkogs of, 418 Hydrogenlike orbitals, 146, 208 Hyperfine splitting constant, 272 I Identity operation, 459 Improper axis, 436 Improper rotation, 436 Independent electron approximation, 127129 Independent π-electron assumption, 246247 INDO, 386t Dally dipole, 411412 Inductive model, 286 Inhomogeneous magnetic field, 133 Inner repulsion energy, 588 Instantaneous dipole moment, 171 Integrals bond, 249 Coulomb, 249, 413, 587590 exchange, 142 list of, 582583 overlap, 249 resonance, 249 Integrand, 472 Intended correlations, 545 To my wife, Ann, and to my late father, William E.
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